Sodium peroxide

If you’re a CHM 100 student, you might have noticed that a part of the oxygen lab that you didn’t get to do involved a compound called sodium peroxide.  Sodium peroxide (Na2O2) is nasty stuff.  It’s a strong oxidizer – which means that it’s dangerous to put into direct contact with anything that burns easily.  It also reacts violently with water.  So what does the lab manual suggest that we do with sodium peroxide?  Sprinkle it onto easily-burned cotton balls and then add water.

No, really.  That’s what the lab manual suggests.  And if you have the Flash plugin installed in your browser (you probably do), here’s what that would look like:

[flv:http://scienceattech.com/wp-content/uploads/2009/09/n2o2_1_lo.flv 320 240]

What’s happening?  The sodium peroxide reacts with water to make hydrogen peroxide and sodium hydroxide.  Plus, you get lots of heat.

Na2O2 + 2H2O –> 2NaOH + H2O2

Then, the hydroegn peroxide formed in the first reaction decomposes to make oxygen.

2H2O2 -> 2H2O+O2

If you did the oxygen lab, you know what the presence of pure oxygen does to combustion!  it’s just too bad that no one told the poor evaporating dish.