Practice FPD Equilibrium 1

Solve the following problems.


1) A solution is prepared by dissolving 2.15 g of sulfur (S8) in 105.0 g of acetic acid (HC2H3O2). What is the freezing point of the solution?



Freezing point of pure acetic acid:

16.60 oC

Kf of acetic acid

3.59 oC/m
















2) An aqueous solution of citric acid (H3C6H5O7) has a concentration of 0.750 m. If the density of the solution is 1.100 g/mL, what is the molar concentration of the solution?












3) Consider the following equilibrium:


N2O4(g) <--> 2NO2(g) ; Kc = 0.125


If you put 0.500 moles of N2O4 in a 10.00 L reaction flask, how many moles of NO2 will be produced at equilibrium? Hint: I am not asking for the concentration of NO 2 as your answer, but you will have to find the concentration to solve the problem. You may need the quadratic formula to solve this problem.


















4) Consider the following equilibrium:


COCl2(g) <--> CO(g) + Cl2(g) ; Kc = 8.05x10-4


You have a vessel filled with 1.50 M COCl2, 0.00050 M CO, and 0.00025 M Cl2. Is the reaction at equilibrium? If it is not, will the reaction proceed to form more products or more reactants?











All original site content ©2008 Charles Taylor. Page updated: February 04, 2008.